Direct asymmetric vinylogous Michael addition of cyclic enones to nitroalkenes via dienamine catalysis.
DOI Number:
10.1073/pnas.1001150107
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
3-methylcyclohex-2-en-1-one, (E)-(2-nitrovinyl)benzene
Product:
(R)-3-(3-nitro-2-phenylpropyl)cyclohex-2-en-1-one
Catalyst:
2-Fluorobenzoic acid, (8α,9S)-9-Aminocinchonan-6′-ol
Cas No:
960050-59-3
Associated Product from Buchler GmbH:
Cupreine Base
Cas No:
524-63-0