Catalytic asymmetric synthesis of chiral γ-amino ketones via umpolung reactions of imines.

DOI Number:

10.1021/jacs.6b09754
Link to literature

Reaction Category:

Further reactions | Isomerization | Umpolung

MOP ID:

MOP_0000789

Educt:

imines, α,β-unsaturated ketones

Product:

γ-amino ketones

Catalyst:

(9S)-9-[(6-chloro-2,5-diphenyl-4-pyrimidinyl)oxy]-1-[[4-(1,1-dimethylethoxy)-3,5-di-2-naphthalenylphenyl]methyl]-cinchonanium bromide

Cas No:

2045210-74-8

Associated Product from Buchler GmbH:

Cinchonine Base

Cas No:

118-10-5