Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis.
DOI Number:
10.1002/anie.201305075
Reaction Category:
Educt:
1-Adamantyl 1-oxoindan-2-carboxylate, 3,3-dimethyl-1-((trifluoromethyl)thio)-1,3-dihydro-1lambda3-benzo[d][1,2]iodaoxole
Product:
Adamantan-1-yl (R)-1-oxo-2-((trifluoromethyl)thio)-2,3-dihydro-1H-indene-2-carboxylate
Catalyst:
Quinine Base
Cas No:
130-95-0
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0