Enantioselective Addition of a Trifluoromethyl Anion to Aryl Ketones and Aldehydes.

DOI Number:

10.1055/s-2003-40889

Reaction Category:

MOP ID:

MOP_0000368

Educt:

2-acetyl-5-methoxyphenethyl 3,4-dimethoxybenzoate

Product:

(R)-5-methoxy-2-(1,1,1-trifluoro-2-((trimethylsilyl)oxy)propan-2-yl)phenethyl 3,4-dimethoxybenzoate

Catalyst:

9-hydroxy-1-(1-naphthalenylmethyl)-(9S)-Cinchonanium fluoride (1:1)

Cas No:

637036-85-2

Cas No:

118-10-5