Highly enantioselective α-sulfenylation of 5H-oxazol-4-ones to N-(sulfanyl)succinimides.

DOI Number:

10.1016/j.tet.2014.09.037
Link to literature

Reaction Category:

Sulfenylation

Educt:

5-methyl-2-(naphthalen-1-yl)oxazol-4(5H)-one, 1-((2-bromophenyl)thio)pyrrolidine-2,5-dione

Product:

(S)-5-((2-bromophenyl)thio)-5-methyl-2-(naphthalen-1-yl)oxazol-4(5H)-one

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0