Catalytic Asymmetric Conjugate Addition of Mercaptans to β‐Substituted‐β‐Trifluoromethyl Oxazolidinone Enoates: Access to Chiral Trifluoromethylated Tertiary Thioethers and Thiols.
DOI Number:
10.1002/adsc.201301027
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
β‐substituted‐β‐trifluoromethyl oxazolidinone enoates, mercaptans
Product:
substituted 3-(4,4,4-trifluoro-3-mercaptobutanoyl)oxazolidin-2-one
Catalyst:
3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(9R)-6′-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione
Cas No:
1256245-79-0
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
54-56-2