Aminocatalytic enantioselective 1, 6 additions of alkyl thiols to cyclic dienones: vinylogous iminium ion activation.
DOI Number:
10.1002/anie.201202392
Reaction Category:
Educt:
cyclic dienones, primary thiols
Product:
substituted 3-(2-(methylthio)ethyl)cyclohex-2-en-1-one
Catalyst:
(tert-butoxycarbonyl)-L-valine, (8α,9S)-6′-Methoxy-2′-phenylcinchonan-9-amine
Cas No:
1278571-62-2
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0