Vicinal All‐Carbon Quaternary Stereocenter Construction with Trifluoromethyl Groups via Organocatalytic Asymmetric Cascade Michael/Michael Reaction.

DOI Number:

10.1002/asia.202300931

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

oxindoles, N-protected (E)-3-benzylidenepyrrolidine-2,5-dione

Product:

N-protected ethyl (3aS,4R,5S,6R,6aS)-1,2',3-trioxo-6-phenyl-4-(trifluoromethyl)-2,3,3a,4,6,6a-hexahydro-1H-spiro[cyclopenta[c]pyrrole-5,3'-indoline]-4-carboxylate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7