Enantioselective Formal [3+3] Cycloadditions of Ketones and Cyclic 1‐Azadienes by Cascade Enamine–Enamine Catalysis.

DOI Number:

10.1002/chem.201404550

Reaction Category:

Educt:

ketones, substituted 3-vinylbenzo[d]isothiazole 1,1-dioxide

Product:

substituted (S)-2H-spiro[benzo[d]isothiazole-3,1'-cyclohexan]-3'-one 1,1-dioxide

Catalyst:

salicylic acid, (8α,9R)-6′-Methoxycinchonan-9-amine

Cas No:

189309-10-2

Cas No:

130-95-0