Enantioselective bromination/semipinacol rearrangement for the synthesis of β-bromoketones containing an all-α-carbon quaternary center.
DOI Number:
10.1039/C1SC00295C
Reaction Category:
MOP ID:
MOP_0000551
Educt:
substituted prop-2-en-1-ol, N-bromsuccinimid
Product:
substituted (4s) 4-bromobutan-2-one
Catalyst:
3,4-dimethoxybenzoic acid, (9S)-(9′′S)-9,9′′-[3,6-pyridazinediylbis(oxy)]bis[10,11- dihydro-6′-methoxy-cinchonan
Cas No:
148215-08-1
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8