Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β‐Fluoroketones.
DOI Number:
10.1002/chem.201202444
Reaction Category:
MOP ID:
MOP_0000553
Educt:
substituted (3,4-dihydro-2H-pyran-6-yl)methanol, N-fluorobenzenesulfonimide
Product:
substituted 1-((2S,3S)-3-fluorotetrahydro-2H-pyran-2-yl)ethan-1-one
Catalyst:
(9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[10,11-dihydro-6′-methoxy-cinchonan]
Cas No:
149725-81-5
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8