Chemo‐and Stereoselective Cross Rauhut–Currier‐Type Reaction of Tri‐substituted Alkenes Containing Trifluoromethyl Groups.

DOI Number:

10.1002/chem.201705010
Link to literature

Reaction Category:

Further reactions | Rauhut-Currier

Educt:

tri‐substituted alkenes, (E)-(2-nitrovinyl)benzene

Product:

ethyl (R,Z)-4-cyano-6-nitro-5-phenyl-3-(trifluoromethyl)hex-3-enoate

Catalyst:

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(9R)-6′-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione

Cas No:

1256245-79-0

Associated Product from Buchler GmbH:

Quinidine Base

Cas No:

56-54-2