Collective Total Synthesis of Mavacuran Alkaloids through Intermolecular 1, 4‐Addition of an Organolithium Reagent.

DOI Number:

10.1002/anie.202302461

Reaction Category:

RXNO ID:

RXNO_0000059

Educt:

methyl 2,2-dimethoxy-5-oxopentanoate, substituted 2-(1H-indol-3-yl)ethan-1-amine

Product:

substituted methyl 2,2-dimethoxy-4-(2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indol-1-yl)butanoate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(8α,9S)-cinchonan-9-ylthiourea

Cas No:

890044-38-9

Cas No:

485-71-2