Asymmetric organocatalytic electrophilic phosphination.

DOI Number:

10.1002/anie.201007188

Reaction Category:

Educt:

butyl 2-cyanopentanoate, chlorodiphenylphosphane

Product:

butyl (R)-2-cyano-2-(diphenylphosphaneyl)pentanoate

Catalyst:

(9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)] bis[10,11-dihydro-6′-methoxy-cinchonan]

Cas No:

149725-81-5

Cas No:

1435-55-8