Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes.

DOI Number:

10.1016/j.chempr.2020.03.024
Link to literature

Reaction Category:

Cyclization | Further reactions | Isoxazoline cyclization | Oxysulfonylation | Sulfonylation

MOP ID:

MOP_0000561

Educt:

3-substituted (1Z,3E)-N-hydroxypent-3-enimidoyl, alkyl sulfonyl chloride

Product:

substituted (1S)-1-((R)-3,5-disubstituted-4,5-dihydroisoxazol-5-yl)ethane-1-sulfinate

Catalyst:

N-(9R)-Cinchonan-9-yl-2,3-dihydro- 2,2,4,5,7-pentamethyl-6-benzofuran sulfonamide

Cas No:

2457206-14-1

Associated Product from Buchler GmbH:

Cinchonine Base

Cas No:

118-10-5