Diastereo-and enantioselective catalytic radical oxysulfonylation of alkenes in β,γ-unsaturated ketoximes.

DOI Number:

10.1016/j.chempr.2020.03.024
Link to literature

Reaction Category:

Cyclization | Further reactions | Isoxazoline cyclization | Oxysulfonylation

MOP ID:

MOP_0000561

Educt:

substituted (Z)-but-3-enal oxime, sulfonylchlorides

Product:

substituted sulfonylmethyl-4,5-dihydroisoxazole

Catalyst:

N-(8α,9S)-Cinchonan-9-yl-2,3,5,6-tetramethylbenzenesulfonamide

Cas No:

2457206-13-0

Associated Product from Buchler GmbH:

Cinchonidine Base

Cas No:

485-71-2