Sulfoxonium Ylides in Aminocatalysis: An Enantioselective Entry to Cyclopropane-Fused Chromanol Structures.
DOI Number:
10.1021/acs.orglett.2c02204
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
ethyl (1R,2S,3R)-2-((E)-3-ethoxy-3-oxoprop-1-en-1-yl)-3-(2-hydroxyphenyl)cyclopropane-1-carboxylate
Product:
cyclopropane-fused chromanoles
Catalyst:
N-[3,5-bis(trifluoromethyl)phenyl]-N′-[(9R)-10,11-dihydro-6′-methoxy cinchonan-9-yl]-thiourea
Cas No:
871334-35-9
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8