Organocatalytic Asymmetric Allylic Alkylation of Morita-Baylis-Hillman Carbonates with Diethyl 2-Aminomalonate Assisted by In Situ Protection.

DOI Number:

10.1021/acs.joc.7b02064

Reaction Category:

MOP ID:

MOP_0000369

Educt:

Morita-Baylis-Hillman Carbonates, N-(2-formylphenyl)-4-methylbenzenesulfonamide, diethyl 2-aminomalonate

Product:

1,1-diethyl 3-methyl (S,E)-2-substituted-1-((2-((4-methylphenyl)sulfonamido)benzylidene)amino)but-3-ene-1,1,3-tricarboxylate

Catalyst:

Quinine Base

Cas No:

130-95-0

Cas No:

130-95-0