A Bifunctional β‐Isocupreidine Derivative as Catalyst for the Enantioselective Morita–Baylis–Hillman Reaction and a Mechanistic Rationale for Enantioselectivity.
DOI Number:
10.1002/ejoc.201200405
Reaction Category:
RXNO ID:
RXNO_0000076
Educt:
benzaldehyde, 1,1,1,3,3,3-hexafluoropropan-2-yl acrylate
Product:
1,1,1,3,3,3-hexafluoropropan-2-yl (R)-2-(hydroxy(phenyl)methyl)acrylate
Catalyst:
(3α,9S)-3,9-epoxy-10,11-dihydro-6′-[N-(2,2,2-trichloroacetyl)carbamate] cinchonan-6′-ol
Cas No:
1403618-98-3
Associated Product from Buchler GmbH:
Dihydrocupreidine Base
Cas No:
73522-75-5