Organocatalytic asymmetric Michael-type reaction between β,γ-unsaturated α-keto ester and α-nitro ketone.

DOI Number:

10.1039/C1OB06191G

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

β,γ-unsaturated α-keto esters, α-nitro ketones

Product:

substituted methyl (Z)-2-acetoxy-5-nitropent-2-enoate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7