Diastereodivergent Synthesis of α-chiral tertiary azides through catalytic asymmetric Michael addition.
DOI Number:
10.1021/acs.orglett.0c03178
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
substituted 2-azido-2,3-dihydro-1H-inden-1-one, (E)-4-substituted-2-oxobut-3-enoate,
Product:
α-chiral tertiary azides
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-25-8
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2