Grinding-Assisted Asymmetric Organocatalysis: A Solvent-free Approach to the Formation of Vicinal Quaternary and Tertiary Stereocenters.
DOI Number:
10.1002/ajoc.201200048
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
nitroolefines, beta-ketoesters
Product:
substituted 1-(2-nitro-1-substituted-ethyl)-2-oxocyclopentane-1-carboxylate
Catalyst:
(8α,9R)-9-(Phenylmethoxy)cinchonan-6′-ol
Cas No:
838821-39-9
Associated Product from Buchler GmbH:
Cupreine Base
Cas No:
524-63-0