Enantioselective synthesis of α-stereogenic γ-keto esters via formal umpolung.

DOI Number:

10.1021/ol301112m

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

((nitromethyl)sulfonyl)benzene, α,β-unsaturated ketones

Product:

β-methylester-substituted ketones

Catalyst:

(8α,9S)-6′-Methoxycinchonan-9-amine

Cas No:

168960-95-0

Cas No:

130-95-0