Water‐Enabled Catalytic Asymmetric Michael Reactions of Unreactive Nitroalkenes: One‐Pot Synthesis of Chiral GABA‐Analogs with All‐Carbon Quaternary Stereogenic Centers.
DOI Number:
10.1002/anie.201611466
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
nitroalkenes, S,S-diethyl propanebis(thioate)
Product:
substituted S,S-diethyl 2-(2-nitroethyl)propanebis(thioate)
Catalyst:
3-[[[3,5-Bis(trifluoromethyl)phenyl]methyl]amino]-4-[[(8α,9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1204591-53-6
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7