Stereocontrolled Creation of Adjacent Quaternary and Tertiary Stereocenters by a Catalytic Conjugate Addition.
DOI Number:
10.1002/anie.200461923
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
methyl 2-oxocyclopentane-1-carboxylate, (E)-(2-nitrovinyl)benzene
Product:
methyl (S)-1-((R)-2-nitro-1-phenylethyl)-2-oxocyclopentane-1-carboxylate
Catalyst:
(8α,9R)-9-(Phenylmethoxy) cinchonan-6′-ol
Cas No:
838821-39-9
Associated Product from Buchler GmbH:
Cupreine Base
Cas No:
524-63-0