Stereoselective synthesis of α-fluoro-γ-nitro thioesters under organocatalytic conditions.
DOI Number:
10.1021/acs.orglett.6b02795
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
methyl 2-fluoro-3-((4-methoxyphenyl)thio)-3-oxopropanoate, (E)-(2-nitrovinyl)benzene
Product:
methyl (2R,3R)-2-fluoro-2-(((4-methoxyphenyl)thio)carbonyl)-4-nitro-3-phenylbutanoate
Catalyst:
N-[3,5-bis(trifluoromethyl)phenyl]- N′-(9R)-cinchonan-9-yl-urea
Cas No:
945985-98-8
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5