Highly diastereodivergent synthesis of tetrasubstituted cyclohexanes catalyzed by modularly designed organocatalysts.

DOI Number:

10.1002/anie.201404072

Reaction Category:

MOP ID:

MOP_0000561

Educt:

(E)-7-oxo-7-phenylhept-5-enal, (E)-(2-nitrovinyl)benzene

Product:

(1R,2S,3R,4R)-3-nitro-4-(2-oxo-2-phenylethyl)-2-phenylcyclohexane-1-carbaldehyde

Catalyst:

L-proline, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-25-8

Cas No:

56-54-2