Diastereodivergent Synthesis of α-Chiral Tertiary Azides through Catalytic Asymmetric Michael Addition.
![](https://www.buchler-gmbh.com/wp-content/uploads/Michael-Addition-6.jpg)
DOI Number:
10.1021/acs.orglett.0c03178
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
alpha-azido indanones, beta,gamma-unsaturated alpha-ketoesters
Product:
alpha-chiral tertiary azides
Catalyst:
N-[(8α,9S)-10,11-dihydro-6′-hydroxycinchonan-9-yl]-Phosphoramidic acid diethyl ester
Cas No:
2545785-62-2
Associated Product from Buchler GmbH:
Dihydrocupreine Base
Cas No:
5962-19-6