Organocatalytic stereoselective synthesis of acyclic γ-nitrothioesters with all-carbon quaternary stereogenic centers.
DOI Number:
10.1021/jo500403q
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
4-methoxyphenyl 3-((4-methoxyphenyl)thio)-2-methyl-3-oxopropanoate, (E)-(2-nitrovinyl)benzene
Product:
acyclic γ-nitrothioesters
Catalyst:
N-[3,5-bis(trifluoromethyl)phenyl]-N′-(9R)-cinchonan-9-yl-urea
Cas No:
945985-98-8
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5