Organocatalytic Enantioselective Synthesis of Nitrocyclopropanes Bearing a Thioester Group and Three Stereogenic Centers.
DOI Number:
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
4-methoxybenzyl 2-bromo-3-(ethylthio)-3-oxopropanoate, (E)-(2-nitrovinyl)benzene
Product:
4-methoxybenzyl (2S,3R)-2-bromo-2-((ethylthio)carbonyl)-4-nitro-3-phenylbutanoate, S-ethyl (1R,2R,3R)-2-nitro-3-phenylcyclopropane-1-carbothioate
Catalyst:
3-[[[3,5-bis(trifluoromethyl)phenyl]methyl]amino]-4-[[(9R)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1362169-08-1
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2