Organocatalytic Enantioselective Synthesis of Nitrocyclopropanes Bearing a Thioester Group and Three Stereogenic Centers.

DOI Number:

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

4-methoxybenzyl 2-bromo-3-(ethylthio)-3-oxopropanoate, (E)-(2-nitrovinyl)benzene

Product:

4-methoxybenzyl (2S,3R)-2-bromo-2-((ethylthio)carbonyl)-4-nitro-3-phenylbutanoate, S-ethyl (1R,2R,3R)-2-nitro-3-phenylcyclopropane-1-carbothioate

Catalyst:

3-[[[3,5-bis(trifluoromethyl)phenyl]methyl]amino]-4-[[(9R)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1362169-08-1

Cas No:

56-54-2