α‐Hydroxy ketones as masked ester donors in Brønsted base catalyzed conjugate additions to nitroalkenes.

DOI Number:

10.1002/chem.201705968

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

3-benzyl-3-hydroxy-1-(4-nitrophenyl)-4-phenylbutan-2-one, (E)-(2-nitrovinyl)benzene

Product:

(4R,5S)-2-benzyl-2-hydroxy-6-nitro-4-(4-nitrophenyl)-1,5-diphenylhexan-3-one

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7