Au (I)-Catalyzed Formal Intermolecular Carbene Insertion into Vinylic C (sp2)–H Bonds and Allylic C (sp3)–H Bonds.
DOI Number:
10.1021/acscatal.2c05351
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
3-(2-phenylallyl)benzo[b]thiophen-2(3H)-one, (E)-(2-nitrovinyl)benzene
Product:
(S)-3-((R)-2-nitro-1-phenylethyl)-3-(2-phenylallyl)benzo[b]thiophen-2(3H)-one
Catalyst:
N-(8α,9S)-cinchonan-9-yl-phosphoramidic acid diethyl ester
Cas No:
2892388-91-7
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2