Sugar thiourea catalyzed highly enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinone to β-nitroalkenes.

DOI Number:

10.1039/C2RA22270A

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

2-hydroxynaphthalene-1,4-dione, nitroalkenes

Product:

2-(1-substituted-2-nitroethyl)-3-hydroxynaphthalene-1,4-dione

Catalyst:

N-[(8α,9R)-10,11-Dihydro-6′-methoxycinchonan-9-yl]-N′- (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-thiourea

Cas No:

1422045-41-7

Cas No:

522-66-7