Asymmetric Mannich reactions with in situ generation of carbamate-protected imines by an organic catalyst.

DOI Number:

10.1021/ol062837q

Reaction Category:

RXNO ID:

RXNO_0000032

Educt:

substituted ((phenylsulfonyl)methyl)carbamate, dibenzyl malonate

Product:

substituted dibenzyl 2-((methoxycarbonyl)amino)malonate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-25-8

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-25-8