Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3‐Fluorinated and All‐Carbon Quaternary Oxindoles.

DOI Number:

10.1002/anie.201608752

Reaction Category:

RXNO ID:

RXNO_0000032

Educt:

N/C-substituted-3-fluoroindolin-2-one, N/C-substituted-3-iminoindolin-2-one

Product:

N/C-substituted-(3R,3'S)-3-amino-3'-fluoro-[3,3'-biindoline]-2,2'-dione

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Cas No:

130-95-0