Direct Carbon−Carbon Bond Formation via Soft Enolization: A Biomimetic Asymmetric Mannich Reaction of Phenylacetate Thioesters.
DOI Number:
10.1021/ol101152b
Reaction Category:
RXNO ID:
RXNO_0000032
Educt:
(E)-N-(2-methylbenzylidene)benzenesulfonamide, S-ethyl 2-phenylethanethioate
Product:
S-ethyl (2S,3S)-2-phenyl-3-(phenylsulfonamido)-3-(o-tolyl)propanethioate
Catalyst:
N-[(8α,9S)-10,11-Dihydro-6′-methoxycinchonan-9-yl]-N′-phenylurea
Cas No:
1236212-68-2
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7