Catalytic Enantioselective Access to Dihydroquinoxalinones via Formal α‐Halo Acyl Halide Synthon in One Pot.

DOI Number:

10.1002/anie.202110173

Reaction Category:

RXNO ID:

RXNO_0000044

Educt:

aldehydes, 2-(phenylsulfonyl)acetonitrile, substituted benzene-1,2-diamine

Product:

substituted 3,4-dihydroquinoxalin-2(1H)-one

Catalyst:

Cumene hydroperoxide, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]urea

Cas No:

957770-66-0

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]urea

Cas No:

957770-66-0