Silver‐Catalyzed Asymmetric Dearomatization of Electron‐Deficient Heteroarenes via Interrupted Barton–Zard Reaction.
DOI Number:
10.1002/anie.202107767
Reaction Category:
RXNO ID:
RXNO_0000496
Educt:
1-protected 3-nitro-1H-indole, 2-substituted 2-isocyanoacetates
Product:
substituted 8b-nitro-3,3a,4,8b-tetrahydropyrrolo[3,4-b]indole-3-carboxylate
Catalyst:
2-(diphenylphosphino)-N-[(8α,9S)-6′-methoxycinchonan-9-yl]-benzamide
Cas No:
1630973-03-3
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0