Organocatalytic Direct Enantioselective Hydrophosphonylation of N‑Unsubstituted Ketimines for the Synthesis of α‑Aminophosphonates.

DOI Number:

10.1021/acscatal.2c05953
Link to literature

Reaction Category:

Hydrophosphonylation

Educt:

2,2,2-trifluoro-1-phenylethan-1-imine, diphenyl phosphonate

Product:

diphenyl (R)-(1-amino-2,2,2-trifluoro-1-phenylethyl)phosphonate

Catalyst:

3-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-4-[(4-methoxyphenyl)amino]-3-Cyclobutene-1,2-dione

Cas No:

2892362-73-9

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0