Cinchona– Diaminomethylenemalononitrile Organocatalyst for the Highly Enantioselective Hydrophosphonylation of Ketones and Enones.

DOI Number:

10.1021/acs.orglett.8b02241

Reaction Category:

Educt:

α,β-unsaturated ketones, diphenyl phosphonate

Product:

α-hydroxy phosphonates

Catalyst:

2-[[[[3,5-bis(1,1-dimethylethyl)phenyl]methyl]amino][[(8α,9S)-10,11-dihydro-6′-methoxy-cinchonan-9-yl]amino]methylene]-Propanedinitrile

Cas No:

1841104-58-2

Cas No:

522-66-7