Cinchona-Derived Picolinamides: Effective Organocatalysts for Stereoselective Imine Hydrosilylation.
DOI Number:
10.1002/ejoc.201403180
Reaction Category:
RXNO ID:
RXNO_0000290
Educt:
methyl (E)-3-(4-bromophenyl)-3-((4-methoxyphenyl)imino)propanoate, trichlorosilane
Product:
methyl (S)-3-(4-bromophenyl)-3-((4-methoxyphenyl)amino)propanoate
Catalyst:
2-[[(8α,9S)-cinchonan-9-ylamino]carbonyl]-1-methyl-Pyridinium tetrafluoroborate
Cas No:
1677706-62-5
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2