Promotion of Henry reactions using Cu (OTf) 2 and a sterically hindered Schiff base: access to enantioenriched β-hydroxynitroalkanes.

DOI Number:

10.1016/j.tet.2012.08.029
Link to literature

Reaction Category:

Aldol | Henry | Henry | Nitroaldol

RXNO ID:

RXNO_0000086

Educt:

aldehydes, nitroalkanes

Product:

beta-nitroalcohols

Catalyst:

2,4-bis(1,1-dimethylethyl)-6-[(E)-[[(8α,9S)-6′-methoxycinchonan-9-yl]imino]methyl]-phenol

Cas No:

1401999-56-1

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0