Direct asymmetric vinylogous Michael addition of cyclic enones to nitroalkenes via dienamine catalysis.
DOI Number:
10.1073/pnas.1001150107
Reaction Category:
Educt:
cyclohex-1-ene-1-carbaldehyde, di-tert-butyl (E)-diazene-1,2-dicarboxylate
Product:
di-tert-butyl 1-(3-formylcyclohex-2-en-1-yl)hydrazine-1,2-dicarboxylate
Catalyst:
(8α,9S)-10,11-Dihydro-6′-methoxycinchonan-9-amine
Cas No:
852913-53-2
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7