Organocatalyzed Enantioselective Fluorocyclizations.

DOI Number:

10.1002/ange.201103151

Reaction Category:

MOP ID:

MOP_0000553

Educt:

N-(2-(5-mesityl-1-methyl-1H-indol-3-yl)ethyl)acetamide, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide

Product:

1-((3aR,8aS)-3a-fluoro-5-mesityl-8-methyl-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indol-1(2H)-yl)ethan-1-one

Catalyst:

(8α,9R)-(8′′α,9′′R)-9,9′′-[1,4-Phthalazinediylbis(oxy)]bis[10,11-dihydro-6′-methoxycinchonan] ((DHQ)2PHAL

Cas No:

140924-50-1

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquininyl)phthalazine ((DHQ)2PHAL

Cas No:

140924-50-1