Diastereoselective Synthesis of Less Accessible Fluorine-Containing Acyclic Tetrasubstituted Stereocenters via Electrophilic Fluorination of β,β-Disubstituted Metalloenamines.
DOI Number:
10.1021/acs.joc.4c00306
Reaction Category:
MOP ID:
MOP_0000553
Educt:
(R)-2-methyl-N-((S,Z)-2-methyl-1-phenylbutylidene)propane-2-sulfinamide
Product:
(R)-N-((R,E)-2-fluoro-2-methyl-1-phenylbutylidene)-2-methylpropane-2-sulfinamide
Catalyst:
(8α,9R)-1-fluoro-9-hydroxy-6′-methoxy-Cinchonanium salt with N-(phenylsulfonyl)benzenesulfonamide
Cas No:
1262224-41-8
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0