Design, Synthesis, and Evaluation of a Novel Class of Enantioselective Electrophilic Fluorinating Agents:  N-Fluoro Ammonium Salts of cinchona Alkaloids (F-CA-BF4).

DOI Number:

10.1021/ol006610l

Reaction Category:

MOP ID:

MOP_0000553

Educt:

enolates or silyl enol ehters of 2-methyl-1-tetralone

Product:

(S)-2-fluoro-2-methyl-3,4-dihydronaphthalen-1(2H)-one

Catalyst:

1-fluoro-9-hydroxy-(9S)-Cinchonanium tetrafluoroborate(1-)

Cas No:

313696-51-4

Cas No:

118-10-5