One-pot fluorination and asymmetric Michael addition promoted by recyclable fluorous organocatalysts.

DOI Number:

10.1039/C3RA42501K
Link to literature

Reaction Category:

Fluorination | Fluorination of beta-ketoester | Michael | Michael Addition

MOP ID:

MOP_0000553

Educt:

beta-ketoesters, alkenes, selectfluor

Product:

alpha-fluoro-beta-ketoesters

Catalyst:

N-[(9R)-10,11-Dihydro-6′-methoxycinchonan-9-yl]-N′-[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]-thiourea

Cas No:

1456767-78-4

Associated Product from Buchler GmbH:

Dihydroquinidine Base

Cas No:

1435-55-8