Recyclable Organocatalysts for a One-Pot Asymmetric Synthesis of 2-Fluorocyclohexanols Bearing Six Contiguous Stereocenters.
DOI Number:
10.1002/adsc.201700129
Reaction Category:
MOP ID:
MOP_0000553
Educt:
beta-keto esters, Selectfluor, beta-nitrostyrenes, alpha,beta-unsaturated aldehydes
Product:
2-Fluorocyclohexanols
Catalyst:
N-[(8α,9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-N′-[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]-thiourea
Cas No:
1456767-79-5
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7