Fluorination, 2-oxa allylic alcohols, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide, beta-fluoro ketones, (1S,1'S,3R,3'R,4S,4'S,6R,6'R)-6,6'-((1S,1'S)- ((2,5-diphenylpyrimidine-4,6-diyl)bis(oxy))bis ((6-methoxyquinolin-4-yl)methylene)) bis(3-ethylquinuclidine), Dihydroquinidine Derivative

Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β-Fluoroketones.

DOI Number:

10.1002/chem.201202444

Link to literature

Reaction Category:

Fluorination | Fluorination

MOP ID:

MOP_0000553

Educt:

2-oxa allylic alcohols, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide

Product:

beta-fluoro ketones

Catalyst:

(1S,1'S,3R,3'R,4S,4'S,6R,6'R)-6,6'-((1S,1'S)- ((2,5-diphenylpyrimidine-4,6-diyl)bis(oxy))bis ((6-methoxyquinolin-4-yl)methylene)) bis(3-ethylquinuclidine)

Cas No:

149725-81-5

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Associated Product from Buchler GmbH:

Dihydroquinidine Base

Cas No:

1435-55-8