The cinchona primary amine-catalyzed asymmetric epoxidation and hydroperoxidation of α, β-unsaturated carbonyl compounds with hydrogen peroxide.
DOI Number:
10.1021/ja402058v
Reaction Category:
MOP ID:
MOP_0000671
Educt:
2-benzylacrylaldehyde, hydrogen peroxide
Product:
(R)-2-benzyloxirane-2-carbaldehyde
Catalyst:
(8α,9S)-6′-methoxy-Cinchonan-9-amine-2,2,2-trifluoroacetate (1:2)
Cas No:
1228358-69-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0